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- Dr. D.Y. Patil Institute of TechnologyPimpri, Pune - 411 018Department of Electrical EngineeringSubject: Audit CourseName:___________________________________________Class:___________________________________________Roll No:_______________Name of Audit Course Selected: Energy Storage Systems
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- 1Energy Storage TechnologiesI. Options for energy storageBecause solar energy supply is variable in time, energy storage is an important issue. Energy storage isused to collect the energy generated by the solar conversion systems (thermal or photovoltaic) in orderto release it later on demand. This can be a situation when sufficient power is produced during the day,and stored energy is used during the night. Also, when insolation conditions are ideal, the solar systemmay produce enough power for the target application, but on dull days, direct energy supply fromcollectors is diminished, and the energy from the storage is used to compensate the deficit. Energy storagedevices help to smooth out differences and minor fluctuations in energy supply caused by shading,passing clouds, etc. Development of efficient and cost-effective energy storage is considered the mainbottleneck of the universal development of solar systems.There are quite a few different technology options for energy storage, which are briefly outlined below:1) Grid. For grid connected solar systems, the most natural and cost-effective way would be to storeenergy in the grid. The main idea here is that the DC power from a solar facility (array or farm) isconverted to AC power and is fed to the grid and further on is used for on-site or off-site applications.This way the grid acts as the medium that collects energy from different power-making facilities(renewable or non-renewable) and redistributes it as necessary. Since a grid does not really representa separate system that is part of a solar plant, it will not be discussed further in this lesson.2) Fluid. Fluid-based storages are typically used with solar thermal systems. Unlike grid which storeselectrical energy, fluids store thermal energy. Fluids, such as water, oil, molten salt or others act as amedium for absorbing heat. The main idea is that the solar radiation heats the heat-transfer fluidwhich is accumulated in the tank. The tank is insulated, so the hot fluid keeps its temperature for asubstantial period of time. When needed, the heated fluid is used in a heat-exchanger to producesteam for the electric generator. This type of thermal energy storage was discussed in more detail inLesson 8.3) Battery. A battery is an electrochemical device that stores chemical energy in internal componentsand releases energy as electricity, which is generated through electrochemical reactions. Batteries arereversible, i.e., can be charged and discharged, and the parameters of these processes are regulatedto avoid damage by overcharging or over-discharging. Battery life is expressed in number of charge-discharge cycles. There are many different types of batteries, some of which will be discussed furtherin this lesson.4) Hydrogen. The idea behind hydrogen storage is that electricity generated by solar PV systems can beused to electrolyze water - to split it to hydrogen and oxygen. Further, hydrogen gas is collected andcan be used as a fuel. One of highly efficient devices "converting" hydrogen back to electricity isH2/O2fuel cell, which has zero carbon footprint during operation.5) Compressed air. In this case, the electrical energy produced by a PV solar system is used to runcompressors to compress massive amounts of air and store it in underground, above-ground, orunderwater containers. Later on, when energy is needed, the air is de-compressed and is supplied toa turbine to generate electricity. Compressed air energy systems (CAES) promise high efficiencies,although this technology is not yet widely implemented.6) Pumped storage hydropower. The available energy can be used to pump water into an elevatedreservoir for storage. When power is needed, the water can be discharged under gravity to run aturbine, which is connected to a generator to produce electricity. The same as compressed air systems,
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- 2the pumped storage technology has high energy return on investment, although it may require specialtopographical conditions and water availability in order to be used.All of the above options for energy storage should be employed with understanding the facility needsand capacity. What energy storage is efficient for small residential systems may be insufficient or toocostly when scaled up to the utility-size systems. Determining capacity of energy storage for a particularsolar project is an important technical and economic issue. For example, if the capacity of the storage istoo large compared to the energy produced by the solar conversion facility, the total system cost will beunnecessarily increased. On the contrary, if the capacity of the storage is too small, that leads to energydumping and overall unsatisfactory plant performance.II.Battery storageBatteries are commonly used to store electric energy generated by off-grid renewable energy systemsand also to mitigate the sharp fluctuations of power for on-grid systems. While there are many differenttypes of battery technologies, some are more applicable to utility scale energy storage than others.Applicability to large systems depends on such factors as cost of materials, ability to scale up with no illeffects or performance loss, and design and operation mode. Some well-known examples of battery typesused as stationary storage system for PV solar are listed in Table.Table 1: Battery types used as stationary storage system for PV solarTechnology(battery type)Power subsystemcost $/kWEnergy storagesubsystem cost $/kWCharge-dischargeefficiency %CyclesAdvanced lead-acid400330802,000Sodium/sulphur350350753,000Lead-acid withcarbon enhancedelectrodes4003307520,000Zinc/bromine400400703,000Vanadium redox400600655,000Li-ion (large)400600854,000Flywheels (highspeed composite)6001,6009525,000Super capacitors50010,0009525,000Note: The costs in the table are based on standard assumptions for the applications and technologiesconsidered, and on expert opinion. They are meant to be used for comparative purposes. The actual costsof any storage system depend on many factors and the assumptions and the means of calculating someof the values are subjective and continue to be debated, even among experts in the fieldFor quite a while, lead-acid batteries have been the first choice for off-grid PV applications. Thislead-acid battery technology has been around since the 19th century and, historically, service providershave more knowledge and tools to deal with those systems. But, despite their long existence andwidespread use, lead-acid batteries remain one of the lowest energy-to-weight and energy-to-volume
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- 3battery designs, which means they are too big and heavy for the amount of energy they provide. Thistechnology is inexpensive and reliable, and it may be a while before it is replaced by more advancedtypes on a wide scale.A) Li-ion battery technologyLi-ion battery is one of the rapidly advancing technologies preferred for employment in conjunctionwith solar systems due to high storage capacity, high charging rates, light weight, and relatively longservice life. However, the technology cost is still high and can be a limitation on the utility scale. Someof the very attractive features of Li-ion batteries are high power output and high charge-dischargeefficiency. They can also withstand more charge-discharge cycles than lead-acid batteries. The principleof operation of the Li-ion battery is discussed below.A schematic representation of a generic Li-ion battery is given in Figure 1. Roughly, Li-ion cellconsists of three layers: electrode 1 (cathode) plate (usually lithium cobalt oxide), electrode 2 (anode)plate (usually carbon), and a separator. The electrodes inside the battery are submerged in an electrolyte,which provides for Li+ ion transfer between the anode and cathode. The electrolyte is typically a lithiumsalt in an organic solvent.Figure 1. Li-ion battery system and charge transfer processesDuring the charging process, a DC current is used to withdraw Li+ions from the cathode and topartially oxidize the cathode compound: LiCoO2→ Li1-xCoO2+ xLi++ xe–The released Li+ions migrate through electrolyte towards the anode, where they become absorbed in theporous carbon structure: xLi++ xe–+ C6→ LixC6At the same time, electrons travel through the external circuit (electrolyte is not electronconductive). During the battery discharge, the reverse process takes place. Li+ions spontaneously returnto the cathode, where electrochemical reduction occurs.Limitations of the Li-ion batteries are rooted in the material properties. For example,the LiCoO2⇔ Li1-xCoO2conversion is only reversible with x < 0.5, which limits the depth of thecharge-discharge cycle. But with a wider variety of materials available, research is underway to developnew generations of Li-ion batteries.
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- 4AdvantagesLimitations1. Relatively high energy density and potentialof finding even better formulations.1. Circuit protection needed to avoid damaging highvoltage / current.2. No need for priming - new battery is readyto operate.2. Aging - battery gradually loses its capacity even ifnot in use.3. Low self-discharge (compared to other typesof batteries).3. Toxic chemicals are subject to regulations.4. Low maintenance.4. High cost of materials and manufacturing process.5. Capability to generate high current / power.5. Technology is not fully mature; varyingcomponents and chemicals.B) Flow BatteriesFlow batteries, unlike solid-state batteries, have their chemical components dissolved in liquidsolutions, which can be pumped through the electrodes in a flow. If you are familiar with the concept offuel cell, it is something similar in principle of operation, although it is still a closed loop system. A flowbattery cell itself can be small, while the solutions can be contained in external storages. One of theadvantages of the flow batteries is almost instant replacement of the electrolyte liquid, thus eliminatingany gradient or concentration fluctuations at the electrodes. The main difference between theconventional batteries and flow batteries is that the energy is typically stored in the liquid phase in flowbatteries. So, increasing the size of the storage tanks for the liquids allows easy scale-up of the battery tomatch a specific application.i) Zinc-bromine flow battery storageZinc-bromine battery is a type of hybrid flow battery. It uses zinc bromine as the workingsolution, which is stored in two compartments, separated by a porous membrane. One compartment hasa negative zinc electrode and the other compartment has a positive bromide electrode. During charge,supplied electricity (e.g., from a solar conversion system) is used to electroplate metallic zinc (Zn) onthe negative electrode, while bromine (Br2) is generated on the positive electrode. During discharge, theopposite process occurs: Zn is dissolved to form Zn2+ions in solutions, and bromine is converted backto bromide ions (Br-).Here are the electrochemical reactions involved in this process:Zn2++ 2e-→ Zn(s) - Reduction of zinc during battery charging2Br-→ Br2(aq) + 2e-- Oxidation of bromine during battery chargingThe overall reaction is therefore: Zn2++ 2Br-⇔ Zn(s) + Br2(aq)This reaction proceeds to the right on charging and to the left on discharging. The standardelectrode potential for the overall reaction is 1.85 V, which is the maximum theoretical voltage that canbe expected from a single cell. The battery cells are stacked to increase the overall storage capacity ofthe system.The battery compartments are made of inert plastic. Unlike common batteries, which storeelectrolyte within the reaction chamber, zinc-bromine batteries have solution storage in the externaltanks, from where it is circulated through the electrodes (flow battery type). The external bromidesolution storage also helps maintaining required concentration of bromide throughout the reaction cycle.
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- 5This technology has been commercialized by ZBB EnerStore company, which engineered zinc-bromine batteries into 50 kWh modules scalable up to bigger storage systems. Each module is a stand-alone system that includes all necessary software and hardware. Some advantages of this technologyinclude high energy density (75-85 Wh/kg), stability, i.e., good resistance to performance degradation,ability to operate at full output within a wide temperature range. Unlike most batteries, ZBB EnerStorebatteries use non-reacting electrodes (i.e., electrodes are not reactants, but simply are substrates forreactions to take place), which helps minimize loss of performance from repeated cycling.ii) Vanadium Redox Flow BatteriesThis type of battery utilizes the multiple redox states of vanadium (V) in its charge-dischargecycles. Vanadium is present in the dissolved form in the sulfuric acid medium, and because it is all-vanadium system, this type of battery is not susceptible to performance loss due to cross contamination.During charging, the following half-reactions occur in two separate compartments of the battery:V3++ e– → V2+VO2++ H2O → VO2++2H++ e–Electrons are supplied from the solar energy conversion system as DC current onto non-reactingelectrode dipped in the V3+solution. As a result V3+is reduced to V2+. At the same time in the othercompartment, vanadium (IV) species VO2+is oxidized to vanadium (V) species VO2+, releasing theelectron. On discharging, these reactions are reversed.The summary process is expressed through the following reaction:VO2++ V3++ H2O ⇔ V2++ VO2++ 2H+The total voltage generated by a single vanadium redox flow battery is around 1.25 V in ideal case.The main benefits of the vanadium redox flow batteries are ability to go through "unlimited"number of cycles; they have a long lifespan (>20 years), quick charging, and high efficiency of thecharge-discharge cycle (~80%). They are also more environmentally friendly in terms of componenttoxicity than many other types of batteries.The vanadium redox flow battery technology is potentially suitable for extra-large utility scaleapplications. For example, the 200 MW VRB battery facility in Dalian, China, is expected to significantlyincrease the stability of the electric grid by supplying power during peak hours and emergency black-starts. Development of such a mega facility was enabled by its co-location with the VFB cellmanufacturing factory, which is tapping into local vanadium resources. The Dalian battery is expectedto become operational in 2020. Nearby wind power facilities have been forced to curtail electricityproduction – this battery facility hopes to reduce curtailing significantly.C) Compressed Air StorageCompressed air storage technology may become an efficient solution of storing energy generated bylarge solar plants. Air is used as the energy transfer medium. During the daytime, solar power is used toheat and compress air in an airtight chamber. When energy is needed, that compressed air can beexpanded through a turbine or another expansion device to drive a generator to create electricity.Compressed Air Energy Systems (CAES) have been in use in some conventional power plants, and theyare making a come-back as energy storage systems for renewable energy plants.Traditionally CAES technology used underground geological formations, such as salt caverns, asreservoirs for compressed air. While this approach was effective at some locations, it was not universal,as geology in some areas may be just unsuitable. A newer approach with CAES is to use human-madechambers - large pipes, such as those used for natural gas pipelines. While it involves more construction
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- 6and installation, this type of artificial storage can be employed virtually anywhere and scaled up to therequired capacity by simply using longer pipes.D) Pumped Hydro Energy StoragePumped-storage hydropower (PSH) is the type of storage technology that is based on storingenergy in the form of potential energy of water. It consists of two water reservoirs at placed at differentelevations connected by discharge channel. The available energy can be used to pump water to the upperreservoir (recharge phase), and energy is released when water moves back down to the lower reservoirthrough turbine (discharge).Closed loop PSH storage does not need to be connected to an outside natural body of water, andall the water is re-circulated.This storage technology is not new. The first commercial systems employed for storage wereimplemented in 1970s, and the design changed very little since then. According to U.S. DOE, pumped-storage currently accounts for 95% of all utility-scale energy storage in the United States. However,additional investments are considered in innovative pumped storage technologies to explore its potentialfor storing non-dispatchable renewable power generated from utility scale wind and solar farms andimproving grid resiliency and reliability.E) Hydrogen storageHydrogen (H2) is a common industrially used chemical and fuel, which can be obtained fromwater by electrolysis or by reforming of natural gas. Electrolysis is of special interest in the energy storagecontext, since it converts electric energy into something storable. The process of electrolysis involvespassing electric current through water or another aqueous solution, which initiates the electrochemicalreaction: H2O ⇔ H2+ 1/2O2The basic idea is that the electricity generated by solar PV systems during daytime can be usedto run electrolyzers to split water into hydrogen and oxygen gases. Hydrogen is collected and stored inone or another form. When energy is needed, hydrogen can be used for combustion or for electrochemicalconversion (in a fuel cell) to recover energy as heat or electricity. Hydrogen provides a new form ofenergy economy, which complies with the present-day environmental requirements. For instance,hydrogen combustion does not result in any carbon emissions, and water and heat are the only products.Electrochemical utilization of hydrogen in fuel cells is thermodynamically efficient and environmentallybenign. Fuel cells can be used for both stationary power generation and transportation. Unlike otherforms of energy storage, hydrogen can be transported and used at a different location.There are a few advantages of the hydrogen energy storage in solar plants:1. Hydrogen generation by electrolysis is a well-established technology. Hydrogen is used in multiplebranches of industry, so the procedures for its handling are well developed.2. Water electrolysis uses low-voltage DC current, which is compatible with the output from the PVcells.3. Hydrogen can be stored with minimal losses.4. Hydrogen can have multiple uses - electricity generation, heat and power generation.5. Hydrogen is environmentally benign substance, its combustion does not produce harmful emissions,it is volatile and is easily dissipated.6. There are multiple ways of hydrogen transportation (pipelines, tanks, hydride compounds).7. Existing infrastructure for natural gas can be adapted to hydrogen use.
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- 7F) Flywheel Energy Storage Systems (FESS)Flywheel energy storage systems (FESS) use electric energy input which is stored in the form ofkinetic energy. Kinetic energy can be described as “energy of motion,” in this case the motion of aspinning mass, called a rotor. The rotor spins in a nearly frictionless enclosure. When short-term backuppower is required because utility power fluctuates or is lost, the inertia allows the rotor to continuespinning and the resulting kinetic energy is converted to electricity. Most modern high-speed flywheelenergy storage systems consist of a massive rotating cylinder (a rim attached to a shaft) that is supportedon a stator – the stationary part of an electric generator – by magnetically levitated bearings. To maintainefficiency, the flywheel system is operated in a vacuum to reduce drag. The flywheel is connected to amotor-generator that interacts with the utility grid through advanced power electronics.Some of the key advantages of flywheel energy storage are low maintenance, long life (someflywheels are capable of well over 100,000 full depth of discharge cycles and the newest configurationsare capable of even more than that, greater than 175,000 full depth of discharge cycles), and negligibleenvironmental impact. Flywheels can bridge the gap between short-term ride-through power and long-term energy storage with excellent cyclic and load following characteristics.Typically, users of high-speed flywheels must choose between two types of rims: solid steel orcarbon composite. The choice of rim material will determine the system cost, weight, size, andperformance. Composite rims are both lighter and stronger than steel, which means that they can achievemuch higher rotational speeds. The amount of energy that can be stored in a flywheel is a function of thesquare of the RPM making higher rotational speeds desirable. Currently, high-power flywheels are usedin many aerospace and UPS applications. Today 2 kW/6 kWh systems are being used intelecommunications applications. For utility-scale storage a ‘flywheel farm’ approach can be used tostore megawatts of electricity for applications needing minutes of discharge duration.How Flywheel Energy Storage Systems WorkFlywheel energy storage systems (FESS) employ kinetic energy stored in a rotating mass withvery low frictional losses. Electric energy input accelerates the mass to speed via an integrated motor-generator. The energy is discharged by drawing down the kinetic energy using the same motor-generator.The amount of energy that can be stored is proportional to the object’s moment of inertia times the squareof its angular velocity. To optimize the energy-to-mass ratio, the flywheel must spin at the maximumpossible speed. Rapidly rotating objects are subject to significant centrifugal forces however, while densematerials can store more energy, they are also subject to higher centrifugal force and thus may be moreprone to failure at lower rotational speeds than low-density materials. Therefore, tensile strength is moreimportant than the density of the material. Low-speed flywheels are built with steel and rotate at rates upto 10,000 PRM.More advanced FESS achieve attractive energy density, high efficiency and low standby losses(over periods of many minutes to several hours) by employing four key features: 1) rotating mass madeof fiber glass resins or polymer materials with a high strength-to-weight ratio, 2) a mass that operates ina vacuum to minimize aerodynamic drag, 3) mass that rotates at high frequency, and 4) air or magneticsuppression bearing technology to accommodate high rotational speed. Advanced FESS operate at arotational frequency in excess of 100,000 RPM with tip speeds in excess of 1000 m/s. FESS are bestused for high power, low energy applications that require many cycles.Additionally, they have several advantages over chemical energy storage. They have high energydensity and substantial durability which allows them to be cycled frequently with no impact toperformance. They also have very fast response and ramp rates. In fact, they can go from full discharge
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- 8to full charge within a few seconds or less. Flywheel energy storage systems (FESS) are increasinglyimportant to high power, relatively low energy applications. They are especially attractive forapplications requiring frequent cycling given that they incur limited life reduction if used extensively(i.e., they can undergo many partial and full charge-discharge cycles with trivial wear per cycle).FESS are especially well-suited to several applications including electric service power qualityand reliability, ride-through while gen-sets start-up for longer term backup, area regulation, fast arearegulation and frequency response. FESS may also be valuable as a subsystem in hybrid vehicles thatstop and start frequently as a component of track-side or on-board regenerative braking systems.G) SupercapacitorsSupercapacitors are a type of energy storage device that is superior to both batteries and regularcapacitors. They have a greater capacity for energy storage than traditional capacitors and can deliver itat a higher power output in contrast to batteries. These characteristics, together with their long-termstability and high cyclability, make supercapacitors an excellent energy storage device. These arecurrently deployed in a variety of applications, either in conjunction with other energy storage devices(mostly batteries) or as self-contained energy sources. Owing to their high conductivity and surface area,porous carbons are being employed in the electrodes of commercial supercapacitors.Types of supercapacitorsA supercapacitor's primary role is to accumulate energy via the spread of charged ions in theelectrolyte on the electrode surfaces. The first type of supercapacitor, the electrical double layercapacitor, supports the reversible electrostatic buildup of ions on the surface of a porous electrode. Thiscategory includes carbon compounds with a large surface area. Second, the pseudocapacitor categoryincludes the reversible redox reaction with electrolyte ions, which ions react with surface functionalmoieties. Pseudocapacitive energy storage is made up of a few oxide compounds of transition metals likemanganese and ruthenium, conducting polymers and hetero-atom-doped carbon compounds.The third form, a hybrid capacitor, is essentially a mixture of a faradaic battery-type electrodeand a non-faradaic electrical double layer capacitor-type electrode. The faradaic battery electrode is madeup of sulfides, transition metal oxides and phosphides, among other materials. Moreover, battery-typeelectrodes are frequently confused with pseudocapacitive electrodes, despite the fact that their chargestorage mechanisms are fundamentally different. Pseudocapacitive charge storage is achieved using ahighly reversible surface redox reaction that does not require phase transition. On the contrary, battery-type electrodes store charge via a reversible faradaic process in which the charged and dischargedelectrodes undergo a phase transition.Pros and cons of supercapacitorsAs a novel kind of energy storage, the supercapacitor offers the following advantages:1. Durable cycle life. Supercapacitor energy storage is a highly reversible technology.2. Capable of delivering a high current. A supercapacitor has an extremely low equivalent seriesresistance (ESR), which enables it to supply and absorb large amounts of current.3. Extremely efficient. The supercapacitor is an extremely energy-efficient component. When chargingand discharging them, very little charge is lost.4. Temperature range is extensive. The temperature range of a supercapacitor is far wider than that of abattery, ranging from -40° C to 70° C.5. State of charge is effortlessly monitored. Calculating the state of charge of a battery is critical forbattery system design, involving sophisticated data collecting and complex algorithms. In comparison,
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- 9determining the state of charge of supercapacitors is quite straightforward, as the energy stored isdependent on only capacitance and voltage, with capacitance being a constant factor.6. Voltage range is extensive. The supercapacitor is capable of running at any voltage less than itscontinuous operating voltage.The key drawback of a supercapacitor is that its cell voltage is quite low. Multiple cells areconnected in series to achieve larger voltages, which may create further issues. However, such problemscan be resolved by load leveling and voltage balance technologies.Applications of supercapacitorsSupercapacitors are used as standalone energy sources or in conjunction with other devices. Thefollowing are some of the devices that are making use of supercapacitors:• Portable devices. Supercapacitors are employed as an energy source in portable screwdrivers andcamera flashes, as they require only bursts of energy and speedy and continuous recharging.• Memory backups. Supercapacitors with a rapid response time provide a temporary solution to amomentary interruption of the memory's power source.• Decoupling of energy and power requirements. Supercapacitors are employed to meet energyrequirements while a different system provides the primary source of energy. Decoupling of this type isused in hybrid and electric automobiles.• Regeneration devices. Supercapacitors can recover energy released by machines that perform repetitiveand steady movements. They are found in a variety of applications, including elevators and cranes, aswell as in the braking systems of electric or hybrid vehicles such as buses, trains, and delivery or garbagetrucks.• Electrical energy distribution and storage. Supercapacitors are capable of compensating for short-duration fluctuations in voltage signals in the distribution line and for bridging the gap betweenproduction and consumption of electricity. Additionally, supercapacitors are utilized to restart powersystems that have failed or to provide energy until the original source is reinstated. Supercapacitors arealso employed as energy storage devices in renewable generation plants, most notably wind energy, dueto their low maintenance requirements.Superconducting magnetic energy storageSuperconducting magnetic energy storage (SMES) is the only energy storage technology thatstores electric current. This flowing current generates a magnetic field, which is the means of energystorage. The current continues to loop continuously until it is needed and discharged. Thesuperconducting coil must be super cooled to a temperature below the material's superconducting criticaltemperature that is in the range of 4.5 – 80K (-269 to -193°C).[1] The direct current that flows throughthe superconducting material experiences very little resistance so the only significant losses areassociated with keeping the coils cool.The storage capacity of SMES is the product of the self-inductance of the coil and the square ofthe current flowing through it. The maximum current that can flow through the superconductor isdependent on the temperature, making the cooling system very important to the energy storage capacity.The cooling systems usually use liquid nitrogen or helium to keep the materials in a superconductor state.Applications of SMESSMES is a specific technology with applications that can be applied to transmission networks on theelectrical grid. They have been commercially installed for several large industrial users.[2] AlthoughSMES systems are very expensive, they are extremely efficient, have almost instantaneous charge anddischarge, are easily scale-able, and have little environmental impact.
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