FULL TEST – I Paper-1 [ANSWERS, HINTS & SOLUTIONS]
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- FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.comANSWERS, HINTS & SOLUTIONSFULL TEST –I(Paper-1)Q.No.PHYSICS CHEMISTRY MATHEMATICS1. B B B2. B C A3. A D A4. B D A5. A A C6. A D B7. C B A8. D B C9. B B A10. A A A11. D B C12. B B D13. B A C14. A B A15. B C C16. C A C17. A B A18. C A B19. C C C1.(A) (r, s), (B) (r, s),(C) (q, s), (D) (p, s)A → (q, r) B → (q, r)C → (p, s) D → (p, s)(A) (s), (B) (p),(C) (q), (D) (r)2.(A) (p, s), (B) (p,s),(C) (q, s), (D) (p, s)A → (r, s) B → (r, s)C → (p, r) D → (p, q)(A) (q), (B) (s),(C) (p), (D) (r)3.(A) (p, q, r, s),(B) (q, s) (C) (q, s),(D) (p, q, r, s)A → (q) B → (r)C → (s) D → (p)(A) (q), (B) (s),(C) (p), (D) (r)ALL INDIA TEST SERIESFIITJEEJEE(Advanced)-2014From Classroom/Integrated School Programs7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Studentsfrom Classroom /Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
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- AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.com2PPhhyyssiiccssPART – I1. Now downward force on the right block ismore.mgTTmg2. IC= I0+ M(OC)2= I0+ M(OB2+ BC2) = IB+ M(BC)23. Potential difference across AC is zero asIAC= 05 2I = 0I = 2.5 ALet the resistance of part BC be rApplying KVL10 + 5 2I Ir I = 02.5r = 7.5 r = 3 GE1= 10Vr1= 1E2= 5Vr2= 2ABCAs resistance of part AB = 9 Length AC = 66.7 cm5. Initial energy of electron = 2eVEnergy after formation of hydrogen atom in the ground state= 13.6 eV.Energy released = 2 (13.6) = 15.6 eVhc79315.6 Å6. Threshold wavelength = 5000ÅWork function =hc= 2.48 eVK.E. = eV = 3 eVhC22585.48 Å7.2VPR R =2 22V 300900P 100 currentV 300iR 900 =1A3Let L be the required inductance, then500 1z 3or2 22500(900) x=13LX 1200 1200 1200 1200L 4H150W 2 f2
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- AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.com38. In steady state potential difference across each capacitor = E9. H = 24 420 06t dtEdtR 12 = 64 J14. q1+ q2= 0vA=1 2kq kqkQR 2R 4R vC=1 2kq kqkQ4R 4R 4R vA= vC q1= Q/3 and q2= Q/3q1Qq2BAC15. vA= k0Q Q Q Q3R 2R 12R 16 R 16. vB= k0Q Q Q 5Q6R 2R 12R 48 R 17-19. When current is maximumdi0dt emf across L = 0 and potential difference across the capacitor will be same.From conservation of charge3CV + CV = 6CV0 CV0 V =05CV4Loss in energy of capacitor = energy stored in inductor +V+ VC3CSL Imax=03V3C2 L
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- AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.com4CChheemmiissttrryy PART – II1.Ag I AgI e oE 0.152 VAg e Ag oE 0.800 V Ag I AgI Ecell= 0. 952 VAt eqm,oSP2.303RT 1EKAg I SP SP2.303RT0.952 logK 0.059 logKF SPlogK 16.13 2.2A t on differentiating the equation we get: 1dA2AdA dt or Adt 2A 2 Hence order is -1.3.ABr10.5r 2 . As it lies in the range 0.414 to 0.732. AB has octahedral structure like that of NaCl.A Ba 2 r r 2 1 2 6 pm Volume = a3= (6 pm)3= 216 pm34. 22BaF s Ba aq 2F aq 2sp2sp2KK Ba F FBa Again22spK 2 Ba F sp2KF2 Ba 5.3Co1s22s22p63s23p63d663d4s4p4d3sp hybridisation6. Bond order of2 2N ,N ,NO ,NO,CN and CN are 3, 2.5, 3, 2.5, 3, 2.5 respectively. Higher is bondorder smaller is bond length. Bond order of CO and CO+are 3 and 3.5.7.2Cl /h4 3CH CH Cl MgCl2Br /hBrKCNC N3H OCOOH8.3 2CH CH OOBrH C6H5
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- AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.com5C6H5OBrC6H5OBrO CH3C6H59.3 2O /Zn H OOOOHOHOOHKOHCannizzaro reaction YK+14. o4 2 21 3H H CaSO . H O s H H O g2 2 14 2H CaSO .2H O s 833 kJ mol = + 484 kJ for 1 kg15.o o oH H S = 17920 J mol-1opG 2.303RTlogK 23o42p H OGlogK 7.22 10 p2.303RT 23H Op 8.1 10 atm 16.2H O pp 1, K 1 oG 0 at eqm.oo ooHH T S T 380 KS = 107oC
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- AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.com6MMaatthheemmaattiiccss PART – III1. x2+ y2– 2x – 2y – 1 = 0x2+ y2– 1 = 0Common chord is –2x – 2y = 0 2x + 2y = 0y = –xPoints of intersection of circles are1 1,2 2 2.4k 182k10 2 5P(E)8 7 14C 3. The line can be written as y = mx and curve as x2+ y2= 4Let, C(h, k) be a point on the circles andA 3, 1begiven point then,h 2 33 h 3 2 3 k 2m3 k = 3m – 2Now, this point (h, k) lies on the circle3, 1 AC(h, k)B2(, m)1(0, 0)y = mx 223 2 3 3m 2 4 2 2 29 12 12 3 9m 4 12m 4 2 29 1 m 12 3 m 12 0 2 23 1 m 4 3 m 4 0 2216 3 m 4 3 1 m 4 0 223 m 3 1 m 0 2 23 m 2 3m 3 3m 0 22 3m 2m 0 22m 2 3m 0 m 0, 34. Suppose m is an integer root of x4– ax3– bx2– cx – d = 0 as d 0 m 0(I) m > 0m4– am3– bm2– cm = d d = m(m3– am2– bm – c) d mAlso, m4– am3= bm2+ cm + dm3(m – a) = bm2+ cm + d m > a contradiction(II) m < 0m = –n n4+ an3– bn2+ cn – d = 0
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- AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.com7n4+ n2(an – b) + (cn – d) > 0So, contradictionHence, equation has no integral solution5. (I)21x x2 21 1x 12 4 1 3x2 2 (II) x2– 3x + 2(III)1x 1 x 12 set x can be1 3,4 4 1+1–1+1 32 21 32 2+ – +1 2+ + – – +1+1–1–1+1+121 32 21 32 22–1 1–2x12x2 1x4 12x 12 3x4 6. Required area,/ 20dxA 4 y dtdt = / 220a4 asint cos t dtsint =/ 22 2 204a cos t dt a xxy(0, a)0(0, –a)y7. Distance from origin,2 2 2D x y z where P(x, y, z) is any point on the curveD2= x2+ y2+ z2= x2+ y2+2xy22xy 4xy D = 2 and occurs at point(s)1, 1, 2and1, 1, 2 ,1, 1, 2 ,1, -1, 2 8. Differentiating w.r.t. ‘r’, 2r dr = 2a cos 2 d,2rasin22rrdr cos2 dsin2 dr tan2dr
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- AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.com8So, differential equation of orthogonal trajectory,dr cot 2dr Solvingdrtan2 dr ln(cos 2) = 2 ln r + k r2= c cos 29. Let3 2f x x bx cx 1. f 0 1 0, f 1 b c 0 So,1,0 . So, 1 1 22tan cosec tan 2sin sec 1 1 1 121 2sin 12tan tan 2 tan tan sinsin sin1 sin 22 as sin 0 10.211 zis continuous every where except where 1 + z2= 0 z = i so when |z| < 1 then above points are excluded so f(z) is continuous11. Continuity : for any point z,0 00 0z z z zlim f z lim x x f z . Non differentiable : for any point z, z 0 z 0f z z f z xf ' z lim limz x i y nowx 0y 0xlim 0x i y andy 0x 0xlim 1x i y 12. 112my cos msin x1 x 2 111 x y mcos msin x 2 22 11 x y xy m y 0 2 2n 2 n 1 n n 1 n nn n 11 x y n 2x y 2 y xy n.1.y m y 02 Simplifying we get, 2 2 2n 2 n 1 n1 x y 2n 1 y n m y 0 13. 323dy 3at 2 tdt1 t 3231tdx26adt1 t Nowdydx at t (2)1/314.-16. Here,v 2 KP P P sovPwill make acute angle with all the vectors from2 3 kP , P , ....., P PnPn–1Pn–2PkPmP3P2P1
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- AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.com9So,v 2 3 k 1OP OP OP ..... OP 0 Again, if n is odd n = 2k – 11 2k 1 kOP OP OP NowkOPwill make acute angle with all the vectors from1 2 2k 1OP , OP ..... OP k 1 2 k k 1 2k 1 k kOP OP OP ..... OP OP ..... OP OP OP 1 Now,k 1 2 2k 1 k 1 2k 1OP OP OP ..... OP OP OP ..... OP =1 2 nOP OP ..... OP Again,Vmakes acute angle with all the vectors1 2 7OP , OP , ....... OP So,1 2 7V S OP + OP +.......+ OP 1 V S 1 17. Eigen values are roots of the equation A – X = 0 (A – I)X = 0 |A – I| = 08 402 2 ( – 4)( – 6) = 0 = 4, 618. When = 61 12 2x x8 6 4 2 4 0x x2 2 6 2 4 0 2x1– 4x2= 0 x1= 2x22X C1 19. |A – I| = 01 0 11 2 1 02 2 3 3– 62+ 11 – 6 = 0 = 1, 2, 3,For = 31X C 12 which is orthogonalSECTION – B1. (A) Assume sphere as, x2+ y2+ z2+ 2ux + 2vy + 2wz = 0Now P, Q, R are (–2u, 0, 0), (0, –2v, 0), (0, 0, –2w)So, equation of plane isx y z12u 2v 2w Since it passes through (1, 2, 3)1 2 312u 2v 2w If centre is (x, y, z) (–u, –v, –w) locus is1 2 32x y z (B) Assume equation of sphere as, x2+ y2+ 2ux + 2vy + 2wz = 0
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- AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942website: www.fiitjee.com10It passes through (, 0, 0), (0, , 0), (0, 0 )ru , v= ,2 2 2 Radius = 1 2 2 212 2 2 2+ 2+ 2= 4 if (x, y, z) are coordinates of centroid x , y , z3 3 3 2 2 24x y z9 (C) P (, 0, 0), Q (0, , 0), OPQ = 15º tan 15º =….. (1)Now if sphere is made with PQ as diameter (x – )x + (y – )y + z2= 0 x2+ y2+ z2= ax + by ….. (2)A plane through PQ parallel to z–axis isx y1 ….. (3)Using (1), (2), (3) we get x2+ y2+ z2= (x + y)x y z2= xy(tan 15º + cot 15º) 2z2xy 02 (D) Using family of planes any plane through line of intersection is x + y – 6 + (x – 2z – 3) = 0Now, its distance from centre of sphere is radius 226 331 1 4 , = 1,12 Equation is x + 2y + 2z = 9; 2x + y – 2z = 92. (A) Let p = cos x sin y cos z. As,y z2 , sin (y – z) 0 21 1p cosz sin x y sin x y cos z2 2 As, sin (x – y) 0 and sin (x + y) = cos z 1 1 2 3p 1 cos2z 1 cos4 4 6 8 (B) The equation can be written as218 2 73u 8u 3 0 u6 28 2 7u6 Clearly, u1, u2are negative so1 2x , x2 < x1+ x2< 2 as cot x tan x = 1 = cot xcot x2 =3cotx cot x2 1 23x x2 and another pair, 1 2 1 27x' x' x' , x' 22 x1+1x'+ x2+2x'= 5
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