FULL TEST – I Paper-1 [ANSWERS, HINTS & SOLUTIONS]

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  • FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    ANSWERS, HINTS & SOLUTIONS
    FULL TEST –I
    (Paper-1)
    Q.
    No.
    PHYSICS CHEMISTRY MATHEMATICS
    1. B B B
    2. B C A
    3. A D A
    4. B D A
    5. A A C
    6. A D B
    7. C B A
    8. D B C
    9. B B A
    10. A A A
    11. D B C
    12. B B D
    13. B A C
    14. A B A
    15. B C C
    16. C A C
    17. A B A
    18. C A B
    19. C C C
    1.
    (A) (r, s), (B) (r, s),
    (C) (q, s), (D) (p, s)
    A (q, r) B (q, r)
    C (p, s) D (p, s)
    (A) (s), (B) (p),
    (C) (q), (D) (r)
    2.
    (A) (p, s), (B) (p,
    s),
    (C) (q, s), (D) (p, s)
    A (r, s) B (r, s)
    C (p, r) D (p, q)
    (A) (q), (B) (s),
    (C) (p), (D) (r)
    3.
    (A) (p, q, r, s),
    (B) (q, s) (C) (q, s),
    (D) (p, q, r, s)
    A (q) B (r)
    C (s) D (p)
    (A) (q), (B) (s),
    (C) (p), (D) (r)
    ALL INDIA TEST SERIES
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    Page 1

  • AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    2
    P
    P
    h
    h
    y
    y
    s
    s
    i
    i
    c
    c
    s
    s
    PART – I
    1. Now downward force on the right block is
    more.
    mg
    T
    T
    mg
    2. I
    C
    = I
    0
    + M(OC)
    2
    = I
    0
    + M(OB
    2
    + BC
    2
    ) = I
    B
    + M(BC)
    2
    3. Potential difference across AC is zero as
    I
    AC
    = 0
    5 2I = 0
    I = 2.5 A
    Let the resistance of part BC be r
    Applying KVL
    10 + 5 2I Ir I = 0
    2.5r = 7.5 r = 3
    G
    E
    1
    = 10V
    r
    1
    = 1
    E
    2
    = 5V
    r
    2
    = 2
    A
    B
    C
    As resistance of part AB = 9
    Length AC = 66.7 cm
    5. Initial energy of electron = 2eV
    Energy after formation of hydrogen atom in the ground state
    = 13.6 eV.
    Energy released = 2 (13.6) = 15.6 eV
    hc
    793
    15.6
    Å
    6. Threshold wavelength = 5000Å
    Work function =
    hc
    = 2.48 eV
    K.E. = eV = 3 eV
    hC
    2258
    5.48
    Å
    7.
    2
    V
    P
    R
    R =
    2 2
    2
    V 300
    900
    P 100
    current
    V 300
    i
    R 900
    =
    1
    A
    3
    Let L be the required inductance, then
    500 1
    z 3
    or
    2 2
    2
    500
    (900) x
    =
    1
    3
    L
    X 1200
    1200 1200 1200
    L 4H
    150
    W 2 f
    2

    Page 2

  • AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    3
    8. In steady state potential difference across each capacitor = E
    9. H =
    2
    4 4
    2
    0 0
    6t dt
    E
    dt
    R 12
    = 64 J
    14. q
    1
    + q
    2
    = 0
    v
    A
    =
    1 2
    kq kq
    kQ
    R 2R 4R
    v
    C
    =
    1 2
    kq kq
    kQ
    4R 4R 4R
    v
    A
    = v
    C
    q
    1
    = Q/3 and q
    2
    = Q/3
    q
    1
    Q
    q
    2
    B
    A
    C
    15. v
    A
    = k
    0
    Q Q Q Q
    3R 2R 12R 16 R
    
    16. v
    B
    = k
    0
    Q Q Q 5Q
    6R 2R 12R 48 R
    
    17-19. When current is maximum
    di
    0
    dt
    emf across L = 0 and potential difference across the capacitor will be same.
    From conservation of charge
    3CV + CV = 6CV
    0
    CV
    0
    V =
    0
    5CV
    4
    Loss in energy of capacitor = energy stored in inductor
    +
    V
    +
    V
    C
    3C
    S
    L
    I
    max
    =
    0
    3V
    3C
    2 L

    Page 3

  • AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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    4
    C
    C
    h
    h
    e
    e
    m
    m
    i
    i
    s
    s
    t
    t
    r
    r
    y
    y PART – II
    1.
    Ag I AgI e
    o
    E 0.152 V
    Ag e Ag
    
    o
    E 0.800 V
    Ag I AgI
     E
    cell
    = 0. 952 V
    At eqm,
    o
    SP
    2.303RT 1
    E
    K
    Ag I
    SP SP
    2.303RT
    0.952 logK 0.059 logK
    F
    SP
    logK 16.13
    2.
    2
    A t
    on differentiating the equation we get:
    1
    dA
    2AdA dt or A
    dt 2A 2
    Hence order is -1.
    3.
    A
    B
    r
    1
    0.5
    r 2
    . As it lies in the range 0.414 to 0.732. AB has octahedral structure like that of NaCl.
    A B
    a 2 r r 2 1 2 6 pm
    Volume = a
    3
    = (6 pm)
    3
    = 216 pm
    3
    4.
    2
    2
    BaF s Ba aq 2F aq
    2
    sp
    2
    sp
    2
    K
    K Ba F F
    Ba
    Again
    2
    2
    sp
    K 2 Ba F
    sp
    2
    K
    F
    2 Ba
    5.
    3
    Co
    1s
    2
    2s
    2
    2p
    6
    3s
    2
    3p
    6
    3d
    6
    6
    3d
    4s
    4p
    4d
    3
    sp hybridisation
    6. Bond order of
    2 2
    N ,N ,NO ,NO,CN
    and CN are 3, 2.5, 3, 2.5, 3, 2.5 respectively. Higher is bond
    order smaller is bond length. Bond order of CO and CO
    +
    are 3 and 3.5.
    7.
    2
    Cl /h
    4 3
    CH CH Cl
    
    MgCl
    2
    Br /h
    
    Br
    KCN
    
    C N
    3
    H O
    
    COOH
    8.
    3 2
    CH CH O
    
    O
    Br
    H C
    6
    H
    5

    Page 4

  • AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14
    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    5
    
    C
    6
    H
    5
    O
    Br
    C
    6
    H
    5
    O
    Br
    
    O CH
    3
    C
    6
    H
    5
    9.
    3 2
    O /Zn H O
    
    O
    O
    OH
    O
    H
    O
    O
    H
    KOH
    Cannizzaro reaction
    
    Y
    K
    +
    14.
    o
    4 2 2
    1 3
    H H CaSO . H O s H H O g
    2 2
    1
    4 2
    H CaSO .2H O s 833 kJ mol
    = + 484 kJ for 1 kg
    15.
    o o o
    H H S
    = 17920 J mol
    -1
    o
    p
    G 2.303RTlogK
    2
    3
    o
    4
    2
    p H O
    G
    logK 7.22 10 p
    2.303RT
    2
    3
    H O
    p 8.1 10 atm
    16.
    2
    H O p
    p 1, K 1
    o
    G 0
    at eqm.
    o
    o o
    o
    H
    H T S T 380 K
    S
    = 107
    o
    C

    Page 5

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    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
    website: www.fiitjee.com
    6
    M
    M
    a
    a
    t
    t
    h
    h
    e
    e
    m
    m
    a
    a
    t
    t
    i
    i
    c
    c
    s
    s PART – III
    1. x
    2
    + y
    2
    – 2x – 2y – 1 = 0
    x
    2
    + y
    2
    – 1 = 0
    Common chord is –2x – 2y = 0 2x + 2y = 0
    y = –x
    Points of intersection of circles are
    1 1
    ,
    2 2
    2.
    4
    k 1
    8
    2
    k
    10 2 5
    P(E)
    8 7 14
    C
    3. The line can be written as y = mx and curve as x
    2
    + y
    2
    = 4
    Let, C(h, k) be a point on the circles and
    A 3, 1
    be
    given point then,
    h 2 3
    3
    h 3 2 3
    k 2
    m
    3
    k = 3m – 2
    Now, this point (h, k) lies on the circle
    3, 1 A
    C(h, k)
    B
    2
    (
    , m
    )
    1
    (0, 0)
    y = mx
    2
    2
    3 2 3 3m 2 4
    2 2 2
    9 12 12 3 9m 4 12m 4
    2 2
    9 1 m 12 3 m 12 0
    2 2
    3 1 m 4 3 m 4 0
    2
    2
    16 3 m 4 3 1 m 4 0
    2
    2
    3 m 3 1 m 0
    2 2
    3 m 2 3m 3 3m 0
    2
    2 3m 2m 0
    2
    2m 2 3m 0
    m 0, 3
    4. Suppose m is an integer root of x
    4
    – ax
    3
    – bx
    2
    – cx – d = 0 as d 0
    m 0
    (I) m > 0
    m
    4
    – am
    3
    – bm
    2
    – cm = d
    d = m(m
    3
    – am
    2
    – bm – c)
    d m
    Also, m
    4
    – am
    3
    = bm
    2
    + cm + d
    m
    3
    (m – a) = bm
    2
    + cm + d
    m > a contradiction
    (II) m < 0
    m = –n
    n
    4
    + an
    3
    – bn
    2
    + cn – d = 0

    Page 6

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    7
    n
    4
    + n
    2
    (an – b) + (cn – d) > 0
    So, contradiction
    Hence, equation has no integral solution
    5. (I)
    2
    1
    x x
    2
    2
    1 1
    x 1
    2 4
    1 3
    x
    2 2
    (II) x
    2
    – 3x + 2
    (III)
    1
    x 1 x 1
    2
    set x can be
    1 3
    ,
    4 4
    
    1
    +
    1
    1
    +
    1 3
    2 2
    1 3
    2 2
    + – +
    1 2
    + + +
    1
    +
    1
    1
    1
    +
    1
    +
    1
    2
    1 3
    2 2
    1 3
    2 2
    2
    –1 1
    2x
    1
    2x
    2
    1
    x
    4
    1
    2x 1
    2
    3
    x
    4
    6. Required area,
    / 2
    0
    dx
    A 4 y dt
    dt
    =
    / 2
    2
    0
    a
    4 asint cos t dt
    sint
    =
    / 2
    2 2 2
    0
    4a cos t dt a
    x
    x
    y
    (0, a)
    0
    (0, –a)
    y
    7. Distance from origin,
    2 2 2
    D x y z
    where P(x, y, z) is any point on the curve
    D
    2
    = x
    2
    + y
    2
    + z
    2
    = x
    2
    + y
    2
    +
    2
    xy
    2
    2xy 4
    xy
    D = 2 and occurs at point(s)
    1, 1, 2
    and
    1, 1, 2
    ,
    1, 1, 2
    ,
    1, -1, 2
    8. Differentiating w.r.t. ‘r’, 2r dr = 2a cos 2 d,
    2
    r
    a
    sin2
    2
    r
    rdr cos2 d
    sin2
    d
    r tan2
    dr

    Page 7

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    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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    8
    So, differential equation of orthogonal trajectory,
    d
    r cot 2
    dr
    Solving
    dr
    tan2 d
    r
    ln(cos 2) = 2 ln r + k r
    2
    = c cos 2
    9. Let
    3 2
    f x x bx cx 1. f 0 1 0, f 1 b c 0
    So,
    1,0
    . So,
    1 1 2
    2tan cosec tan 2sin sec
    1 1 1 1
    2
    1 2sin 1
    2tan tan 2 tan tan sin
    sin sin
    1 sin
    2
    2
    as sin 0
    10.
    2
    1
    1 z
    is continuous every where except where 1 + z
    2
    = 0
    z = i so when |z| < 1 then above points are excluded so f(z) is continuous
    11. Continuity : for any point z,
    0 0
    0 0
    z z z z
    lim f z lim x x f z
    . Non differentiable : for any point z,
    z 0 z 0
    f z z f z x
    f ' z lim lim
    z x i y
    now
    x 0
    y 0
    x
    lim 0
    x i y
    and
    y 0
    x 0
    x
    lim 1
    x i y
    12.
    1
    1
    2
    m
    y cos msin x
    1 x
    2 1
    1
    1 x y mcos msin x
    2 2
    2 1
    1 x y xy m y 0
    2 2
    n 2 n 1 n n 1 n n
    n n 1
    1 x y n 2x y 2 y xy n.1.y m y 0
    2
    Simplifying we get,
    2 2 2
    n 2 n 1 n
    1 x y 2n 1 y n m y 0
    13.
    3
    2
    3
    dy 3at 2 t
    dt
    1 t
    3
    2
    3
    1
    t
    dx
    2
    6a
    dt
    1 t
    Now
    dy
    dx
    at t (2)
    1/3
    14.-16. Here,
    v 2 K
    P P P
    so
    v
    P
    will make acute angle with all the vectors from
    2 3 k
    P , P , ....., P
    P
    n
    P
    n–1
    P
    n–2
    P
    k
    P
    m
    P
    3
    P
    2
    P
    1

    Page 8

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    FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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    9
    So,
    v 2 3 k 1
    OP OP OP ..... OP 0
     
    Again, if n is odd n = 2k – 1
    1 2k 1 k
    OP OP OP
    Now
    k
    OP
    will make acute angle with all the vectors from
    1 2 2k 1
    OP , OP ..... OP
    k 1 2 k k 1 2k 1 k k
    OP OP OP ..... OP OP ..... OP OP OP 1
      
    Now,
    k 1 2 2k 1 k 1 2k 1
    OP OP OP ..... OP OP OP ..... OP
        
    =
    1 2 n
    OP OP ..... OP
      
    Again,
    V
    makes acute angle with all the vectors
    1 2 7
    OP , OP , ....... OP
    So,
    1 2 7
    V S OP + OP +.......+ OP 1
    V S 1
    17. Eigen values are roots of the equation A – X = 0 (A – I)X = 0
    |A – I| = 0
    8 4
    0
    2 2
    ( – 4)( – 6) = 0
    = 4, 6
    18. When = 6
    1 1
    2 2
    x x
    8 6 4 2 4 0
    x x
    2 2 6 2 4 0
    2x
    1
    – 4x
    2
    = 0 x
    1
    = 2x
    2
    2
    X C
    1
    19. |A – I| = 0
    1 0 1
    1 2 1 0
    2 2 3
    3
    – 6
    2
    + 11 – 6 = 0 = 1, 2, 3,
    For = 3
    1
    X C 1
    2
    which is orthogonal
    SECTION – B
    1. (A) Assume sphere as, x
    2
    + y
    2
    + z
    2
    + 2ux + 2vy + 2wz = 0
    Now P, Q, R are (–2u, 0, 0), (0, –2v, 0), (0, 0, –2w)
    So, equation of plane is
    x y z
    1
    2u 2v 2w
    Since it passes through (1, 2, 3)
    1 2 3
    1
    2u 2v 2w
    If centre is (x, y, z) (–u, –v, –w)
    locus is
    1 2 3
    2
    x y z
    (B) Assume equation of sphere as, x
    2
    + y
    2
    + 2ux + 2vy + 2wz = 0

    Page 9

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    10
    It passes through (, 0, 0), (0, , 0), (0, 0 )
    r
    u , v= ,
    2 2 2
    Radius = 1
    2 2 2
    1
    2 2 2
    2
    +
    2
    +
    2
    = 4 if (x, y, z) are coordinates of centroid
    x , y , z
    3 3 3
    2 2 2
    4
    x y z
    9
    (C) P (, 0, 0), Q (0, , 0), OPQ = 15º
    tan 15º =
    ….. (1)
    Now if sphere is made with PQ as diameter (x – )x + (y – )y + z
    2
    = 0
    x
    2
    + y
    2
    + z
    2
    = ax + by ….. (2)
    A plane through PQ parallel to z–axis is
    x y
    1
    ….. (3)
    Using (1), (2), (3) we get x
    2
    + y
    2
    + z
    2
    = (x + y)
    x y
    z
    2
    = xy(tan 15º + cot 15º)
    2
    z
    2xy 0
    2
    (D) Using family of planes any plane through line of intersection is x + y – 6 + (x – 2z – 3) = 0
    Now, its distance from centre of sphere is radius
    2
    2
    6 3
    3
    1 1 4
    , = 1,
    1
    2
    Equation is x + 2y + 2z = 9; 2x + y – 2z = 9
    2. (A) Let p = cos x sin y cos z. As,
    y z
    2
    , sin (y z) 0
    2
    1 1
    p cosz sin x y sin x y cos z
    2 2
    As, sin (x – y) 0 and sin (x + y) = cos z
    1 1 2 3
    p 1 cos2z 1 cos
    4 4 6 8
    (B) The equation can be written as
    2
    1
    8 2 7
    3u 8u 3 0 u
    6
    2
    8 2 7
    u
    6
    Clearly, u
    1
    , u
    2
    are negative so
    1 2
    x , x
    2
    < x
    1
    + x
    2
    < 2 as cot x tan x = 1 = cot x
    cot x
    2
    =
    3
    cotx cot x
    2
    1 2
    3
    x x
    2
    and another pair,
    1 2 1 2
    7
    x' x' x' , x' 2
    2
    x
    1
    +
    1
    x'
    + x
    2
    +
    2
    x'
    = 5

    Page 10

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